Seperate channels is the recommended setup by CDR manufacturers such as Plextor.
And it stands to reason ,If both CDRW's are on same channel the constant negotiation for the data to travel from the source drive to the copy drive is a logistical nightmare.
It is like traffic trying to travel in opposing directions at the same time on a single lane road.
Putting each CDRW on a seperate channel raises another problem ,the transfer speed on each channel is dictated by the slowest device on that channel. And CDR drives generally operate at 1/3 of the speed of Ultra ATA drives.
The negative side of having two CDR devices far outweighs the positive of having a single device.
Replace the second device with a Larger Hard Drive and build a library ,If you intend on making more than one copy of your data this will prove much faster.
I have over 50GB's of music on one drive and the ability to mix and match songs without having to shuttle discs back and forth is excellent.