Well, ATM is pretty much dead for new Enterprise networks. Nowadays, it's pretty just a "cloud" technology.
ATM is wunnerful...if you need more bandwidth between switches, you put in another cable, and - up it comes...no hassles with Spanning Tree (with all due respect to R. P., Spanning Tree sucks, IMHO - needed at the time, sucks today), no worries about loops....it just starts using the additional link. It scales better and easier than Ethernet, handles all service types (voice, video, data) easily, and supplies/offers complete Quality of Service from End-to-End. Someday, with MPLS (once the final parts get ratified), Ethernet might have the same QOS offered by ATM five years ago.
Can't say I'd recommend learning ATM, unless you're planning on working with "cloud" elements (Like Frame Relay, SMDS, etc). If that's the case, then the Cisco (former Stratacom) product would be your best focus. Thre are still a lot of companies with ATM at the core of their network - lots of Fore Systems/Marconi (a great way to go), but most of them already have a staff, and are probably planning to move to GigE (or SONET) at the next Network Rev.
I've seen Fore Systems stuff on Ebay for dirt cheap....200BX with (really old - i960) switch processors and a couple four-port netmods for ~$250.00, and 3850s (Ethernet Edge switch) for under $100.00. A similar 200BX, new, was $15,000.00 to $20,000.00 less than two years ago (with newest switch processors). ATM NICs are ~$10-15 a piece, and the more recent ones are directly supported in WIN2K and XP. Drivers are available for 9.x, NT4, Solaris (sparc), and maybe Linux (probably available for Linux).
FWIW
Scott