For games, latency is more important than bandwidth.
Assuming both kits would actually run with those settings, first one would be slightly faster in games (latencies are 13.75ns for DDR4-3200 CL22 vs 14.25ns for DDR4-2666 CL19).
But if you are looking at modules with lower frequency, search for lower CAS latency too. CL19 for DDR4-2666 is not that great.
For instance DDR4-2400 CL15 (12.5ns) should be faster in games than both your choices.
Of course, you probably won't notice the differences while playing. Only visible in benchmarks.