Really hard to say what might actually happen because of her appointment. I could swing from slightly positive to disastrously negative in my mind.
Important to consider charter schools. It's been a common (typically Republican) idea that they are superior to public schools, but it's really hard to draw inferences from the data. Technically there can't be discrimination from a charter school, but in reality there is a huge selection bias of the student population given the requirement of an application. To me, the biggest concern though is the limitations on oversight. There are many cases of fraud and embezzlement, and otherwise schools who are interested in making a profit rather than actually providing an educational environment that is different than a public school. In the worst case, a charter school will fold in the middle of a school year and leave kids behind.
From a curriculum standpoint, clearly I have a lot of scientific educational background, and I am no creationist. Mostly, though, within limits, a good school is not defined by its unbiased curriculum. What matters is a culture of learning, a celebration of curiosity, a platform for developing individual interests, involvement with parents in the community, etc.
Vouchers? Well I'm quite ambivalent about that one. I think there is quite a bit of value in diversity of early life education that may not be measurable scholastically, and of course it's going to cost money to transport students and administer these programs.