Two DFI Ultra-D's used for me and both have been excellent boards, extremely reliable, very nice performance.
My buddy got a DFI SLI Expert - nothing but problems. Cold boot issues, poor RAID performance (something I experienced with my Ultra-D as well, unfortunately), extreme pickiness. The Expert is a b!tch on power supplies too - very few work properly with it. Enermax Noisetaker and OCZ Modstream both had cold boot issues with the DFI Expert board (an OCZ Powerstream worked fine).
I recommended to my friend the new ASUS A8R32-MVP (ATI's RD580 chipset) - great success with the board! Extremely fast, stable and reliable.
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I think DFI is a good brand but they're going to have to keep it up to maintain the reputation. I've heard of many people having problems with the Expert series (though the Ultra-D and SLI-DR were, in my opinion, pure gold!).
One thing (I think this is true for all Nforce4 boards) that annoys me is the horrible RAID 1 performance. RAID 1 (two mirrored discs) performed mediocre for me on my Ultra-D (slower than a single drive!) and RAID 0 + 1 like crap (a tad faster than a single drive, only!!). RAID 0 is very quick on NF4 (as it should be). Plus Nvidia's IDE drivers suck - I don't even bother installing them anymore.
On the RD580, using the ULI chipset, RAID 0 + 1 absolutely flies - performs just like a RAID 0 array, that is, twice the speed of a single disc, only with the security of mirroring as well. RAID 1 performs as it should too (about equal to a single disc).