how complex is the video you are working on? Are you capturing uncompressed video? What formats? Do you work in video editing alot? What software you using? What is your capture method. What are the specs for your computer? What software?
If you work alot in high quality uncompressed video, you should RAID your drives so they run faster. You can run RAID 0 but RAID 5 is the safest, but you will lose 50% of your HD space as it makes redundant (backup) copies.
Uncompressed high quality video like AVI can run 15-25MB/sec. Not only is that a massive amount of space, but its also a very fast transfer rate that many normal drive setups cannot handle. When the drive setup cannot write that fast, you lose frames.
well without going into a video capture primer, you could setup a RAID setup, which may not cost anything if your MB has a RAID controller, or just setup the drives in a normal fashion. The drives you have are fine but I would work off the WD SE's as they will be faster, due to the cache, then the Maxtor.
I'd rather have more info on what you want to do (specifically) before giving you advice. Personally I would RAID (0 or 5) the 180gb WD's.