Originally posted by: ProviaFan
You probably aren't using it seriously with high res images if you think 1GB is enough.
I have an Athlon 64 X2 4400+ with 2GB of RAM, and Photoshop CS2 absolutely flies with my DSLR images and medium res 35mm scans (though I'm not heavy into the manipulation aspect with tons of layers and masks). If she's doing much layering and masking on medium or large format drum scans, then without question 4GB should be chosen.
With that said, running XP64 may be a problem if she prints from the same machine that she uses for PS, because 64 bit printer drivers are basically nonexistent at this point (and Epson in particular is being bad about giving ETAs and not keeping them).
XP32 can still handle 4GB of RAM, but an individual process can only have 2GB of that (except in special circumstances). Photoshop can have 2GB to work on images directly, and the rest can be used for your other programs and/or OS disk caching to store part of the scratch file (I do not mean a RAM disk - let the OS handle the caching of the scratch disk on its own).
That is about it,
xp64 is still a year or more away from being useful in the real world.
and what ProviaFan said about memory use is correct, more than 2G can be a +, even if only 2G is used by any single aplication.
As for the video card, for 2D like photoshop, a Matrox G450 with 16MB ram will work as good or better than an SLI setup, or any more expensive option.
If you are going to do anything 3D, get a card made for 3D, if you are doing 2D graphics, get a card made for that.