Group all of the power cables and connectors together
recommend rerouting them and pulling them as far away from the computer case as possible. This will make it as easy as possible to test the power supply connections.
Short out pins 15 and 16 on the 24-pin motherboard power connector with a small piece of wire (green and black normally)
Plug in the psu
Set your multimeter to VDC. If the meter doesnt have a auto range set it to 10.00v
Test the mobo 24 pin connector first by connecting negative probe on the multimeter (black) to any ground wired pin and connect the positive probe (red) to the first power line you want to test.
24 pin got a +3.3 VDC, +5 VDC, -5 VDC (optional), +12 VDC, and -12 VDC lines across multiple pins. look for any voltages outside the approved tolerance
Unplug it from the wall
reconnect your internal devices remove the short plug in the 24 pin in the mobo
plug it in then test the connectors for your devices simple
Ps I do not take responsibility for any ellectrical shock nor bush fires you might start.