Yeah, not all 4 cores are going to 4.4GHz at stock unless you've enabled an option for it in bios. I think it's called "multi core enhancement" on Asus boards, not sure if it's the same across the board.
I don't believe Tcase is what it's using. TJ max is ~100c, which is probably from the sensor HW monitor is using.
[For OP's TCASE question -- to clarify:]
Back in the day, with Pentium 4, there was only a single temperature sensor. It may have been called "TJunction" or TJ then. Who remembers? I don't.
The TCASE spec may still be included with Haswells. It is essentially a "thermal design" spec or a case guideline that includes ventilation. It is essentially a measurement of temperature dead-center on the IHS, which is really impossible without special provision -- because there's no sensor there.
So TCASE for current-day processors should be about 72.5C.
At some point, someone over at Tom's HW actually did the measurement. This was done for the Conroe and likely the Kentsfield C2Q. I think I read it just when the Wolfies and Yorkies were being released. But the upshot was that the difference between TCASE and the AVG(c0,c1,c2, c3) of TJ measurements was between 10C and 15C.
I use the "guesstimate" of 10C, if I need to worry about it. So, if my 2600K is running at full load with LinX or IBT, showing an average temperature of 73C, then I'm about 10C within the TCASE spec. I assume that the mythical and arcane "spec" links case design and thermal effects on silicon. I wouldn't really know for sure, though.
Look at it another way. Most folks tend to wind up their overclocking project when they can't keep the Tj temperatures lower than 85C. And that -- by my understanding -- is still close to the TCASE spec.