I have a similair cold-boot problem with my k7S5A, about 25% of the time when booting, it stalls (blank screen) after post, CD-ROM spins up, HD spins up, Power LED and all, but just sits there? When I reset it, it boots into WinXP 100% of the time. I'm running a Antec 430watt TruePower p.s so you can throw that out the window as being the culprit. I've fooled around with BIOS settings, power management, ect. - can't seem to fix the problem.
I've heard of the capacitor discharge thing and it very well could be that, I don't know though? This would seem to be the case for me since it always boots into the OS after hitting the reset button (give the board chance to chargeup). I'm going to fool around with BIOS a little more to see if I can't stall the startup just long enough so it will finish posting and boot into the OS - if this is the case then I believe this thing just needs a little time to 'wake-up'.
If it has been running, I can shut it down and it always boots right back up when I want it too. Heh, it's like an old car I use to own, once it's going it goes great, sometimes it has a little trouble starting!
I'm going to be switching memory brands soon with all different flavors of SDR and DDR and see if it makes a difference?
-VTrider