Depending on the context, there are two different ways to think about scaling with percentages.
The first method is the multiplicative method. This is the method used by the "scale" command in most computer graphics programs, like Photoshop. You provide a percentage and the new image is that percentage multiplied by the original image.
For example, if you entered "50%" the new image would be 50% times the original image; that is, half the size of the original image. If you entered "200%" the new image would be 200% times the original image; that is, twice the size of the original image. If you entered "100%" the new image would be exactly the same size as the original image.
The second method is the additive method. This is the method many people use when talking out loud, but personally I think it's a little confusing. In this method you specify the percentage by which to increase the original image. You cannot shrink the image.
For example, if you said "50%" the new image would be 50% bigger than the original image. If you said "100%" the new image would be 100% bigger than the original image; that is, twice the size. If you said "0%" the new image would be 0% bigger than the original image; that is, the new image would be exactly the same size as the original image.
It's easy to convert from multiplicative scaling to additive scaling. To go from multiplicative to additive, subtract 100%. To go from additive to multiplicative, add 100%.
Now let's take your mom's problem. You've got a pattern for a 6" doll and you want to create a pattern for a 10" doll. To get the multiplicative scaling factor, just divide the new size by the old size and multiply by 100. 10"/6" * 100 = 167%. This means that if you were scaling the image in Photoshop you would enter "167%" as the multiplicative scaling factor.
To get the additive scaling factor, subtract 100% from the multiplicative scaling factor. 167% - 100% = 67%. This means that if someone asks you how much bigger should the new pattern be, you would answer "67% bigger".
Now let's figure out why your mom's answer ("50% bigger") was wrong. She said "bigger" so she clearly meant "additive scaling". First, let's convert it to a multiplicative scaling factor by adding 100%. 50% + 100% = 150%. So if she were scaling the pattern in Photoshop she would have entered "150%". Now let's figure out how big her new doll would be. 6" * 150 / 100 = 9". That's too small, so her guess of "50% bigger" was too low.
In conclusion, if your mom is using Photoshop to scale up her pattern, she should enter "167%" as the scale factor. If she's telling someone how much bigger the new pattern should be, she should tell them "67% bigger". If she's drawing a new pattern on paper, she should move her pencil 1.67 inches for each inch of the original pattern.