1/2.
2/3 is the chance of picking two balls of the same color, gold or silver, from the start of the scenario. The question in the OP does not occur at the start of the scenario, but after you have selected a gold ball, the way I am reading it. That means that boxes {G,G} and {G,S} are all that matter to the probability of the next ball's selection. IE, as written in the OP, the {S,S} box is a red herring, since it is no longer a valid option. No amount of reasoning that includes the {S,S} box in the calculation, which will lead to 2/3, is valid, IMO, given the way the question is placed and written. The givens to the problem include that the {S,S} box has already been excluded, so it may as well have just started off with two boxes, {G,G} and {G,S}, instead.
The probability of picking two golds at the start is 1/3. Only after having drawn the first gold ball does the probability increase to 2/3.
I suggest browsing the thread a little. The reason it is 2/3 is given on pretty much every page in various forms and there are 3 independent computer simulations provided to prove it.