Here's what I know about Pex. Sharkbite is actually a brand name. The push on connectors are sometimes known as Sharkbite connectors, but Apollo makes them too.
Pex can bend, but still needs 90 degree elbows to help alleviate tension in the line when turning sharp corners. Wide corners are fine, but in most construction, space is an issue. They make brass and plastic/nylon type elbows/wyes, valves, etc... The brass ones cost double, but are supposed to be no better (according to the guys I've spoken to...maybe they're more reusable if you ever pull the rings off a fitting....but most people would never do that.
There are 2 kinds of crimp bands. You can get copper ones that go around the pipe and compress. (soft metal, crimps more permanent) You can get steel ones that crimp and can be removed with a removal tool. The copper method is the preferred method by me. You can use a tool to measure the width of the fitting and test the crimp to make sure it's compressed enough. The tools are interchangeable between Apollo and Sharkbite. Multi-crimp tools are about $65 to do 1/2" and 3/4".
Finally, pex pipe has two key numbers to be aware of. The temp rating and PSI are important. The pipe can and will fail at high temps or high pressure ratings. The higher either number travels, the less temp or PSI it can handle. So be aware that it is possible to have a blowout if you're using it for high temp/pressure. Pouring a concrete slab around it is ok if you use an oxygen barrier pex. Otherwise, I would sheath it in PVC or conduit, which would also allow you to replace the line at a later date if you must.