<< What is isotopically pure silicon? >>
The most common form of silicon found in a substrate is Si[28] ... this occurs when the number of neutrons in a silcon atom equals the number of protons. Also fairly common are Si[29] and Si[30] which have one and two more neutrons respectively.
It so happens that when Si forms a single-crystal lattice, there is a slight non-uniformity introduced by the fact that the individual atoms are not all identical. By removing the Si[29] and Si[30] isotopes, this irregularity is brought much closer to zero. The beautiful thing about this is that this purer lattice can have FAR GREATER themal conductivity, which means that heat dissipation becomes a much simpler task than before. Of course this means you can increase clock speed without running into problems so quickly, which is why anybody cares.