Even in worst case scenario of explosively opening the door to your space ship wouldn't cause immediate death, because the difference in pressure from the inside of the space ship (probably pressurized to something like that of the inside of a commercial airplane, ~0.75 atm) isn't a huge pressure differential. The worst that would happen would be if you were holding a deep breath, your lungs might rupture. You would become unconscious after 10 seconds, because the blood in your lungs exposed to a vacuum gives up all its air and it takes 10 seconds for this deoxygenated blood to reach your brain. While the water in your mouth would boil, it isn't as bad as it sounds. The moisture isn't hot like a pot of boiling water, it is just evaporating and cooling rapidly. I imagine the sensation would be like eating a mouthful of poprocks and drinking a glass of ice cold water.
I remember reading about an accident involving a diving bell and a decompression chamber where some divers were explosively decompressed from 9 atm to 1 atm. I think their bodies did literally explode, i.e. their limbs blown off and all their internal organs exploding, which doesn't sound like much fun at all.