Sure, it can't hurt to unplug, but another reason is that many, if not most electronic devices these days draw electricity, even if they are turned 'off'. This electricity usage is wasteful.
For instance, most cars have built-in computers that control various aspects of the engine, steering, and other things such as the radios, airbags, etc. Even if engine is turned 'off, these systems are still running, drawing electricity from the battery. Hence, a modern car will exhaust its battery power in the span of days to a couple weeks, and will require a boost or a recharge to start up again.
Whereas, for instance, one of my older cars has almost zero draw when its shut down, because there is no ECU to operate, no phantom loads. So I can walk away from it at the airport for 2 months, come back, turn the key, and it just leaps to life.