PolymerTim
Senior member
- Apr 29, 2002
- 383
- 0
- 0
That's interesting to hear about the pi orbital effect; I hadn't heard about that. I had heard that refractive index is based, in part, on density as well, but I never knew what any other "chemical" factors were. In fact the density effect is the principle behind a detector I use that measures change in refractive index and correlates this linearly with solution concentration in a liquid chromatography setup.
The detail I was trying to figure out based on my last response was if the speed of light in a medium is slower on all length scales. My guess was that the "effective" speed I have seen referred to the apparent speed over lengths larger than, say, a micrometer (I imagine we can't actually measure it over that small a distance any way). But I was wondering if maybe the photons, on a sub angstrom level, kind of skip from one atom to the next at c_o, but then get caught for some time at an atom before moving on to the next one. I now see that's probably wrong though since, if it is actually the electron cloud that is interacting with photons, then I imagine the photons are practically travelling through a sea of them and are probably going a near constant speed even on the sub-angstrom length scale, subject primarily to density fluctuations.
The detail I was trying to figure out based on my last response was if the speed of light in a medium is slower on all length scales. My guess was that the "effective" speed I have seen referred to the apparent speed over lengths larger than, say, a micrometer (I imagine we can't actually measure it over that small a distance any way). But I was wondering if maybe the photons, on a sub angstrom level, kind of skip from one atom to the next at c_o, but then get caught for some time at an atom before moving on to the next one. I now see that's probably wrong though since, if it is actually the electron cloud that is interacting with photons, then I imagine the photons are practically travelling through a sea of them and are probably going a near constant speed even on the sub-angstrom length scale, subject primarily to density fluctuations.