CAV=Constant Angular Velocity
CLV=Constant Linear Velocity
With CAV the writing speed changes as the drive starts writing from the inner to outter tracks, the rotational velocity remains fairly constant.
With Z-CLV the writing speed changes but it is zone based. The inner tracks it will write at one speed, as soon as it hits the next zone, it will slow down and then boom increase the rotational speed and start writing at a higher speed. I think it has 5 zones, I don't remember. You can tell when it is switching to a new zone when it quiets down a little and then makes a sound like a jet engine taking off. In CD Speed, this will show up as spikes in the speed. It will be writing at 22x at one point and then boom, it starts writing at 31x and then 40x and then 48x. So for a given zone, the write speed is constant...hence constant linear velocity and since it is zone based, it's called Z-CLV.
CAV is faster since it doesn't need to slow down to change speeds, it keeps a constant rotational speed so it doesn't have those spikes that show up in CD Speed when using Z-CLV.
Hope that helps