I don't have much experiance with it in terms of HDTV.
But here are some clues:
In your Xorg.conf you will find several sections. The ones you care about are the Monitor section and the Screen section.
For the monitor section here is what I use for my laptop:
Section "Monitor"
Identifier "COLOR LCD"
Option "DPMS"
HorizSync 28-51
VertRefresh 43-60
EndSection
The Identifier is important to leave alone as it's used in other sections of the configuration file. (if you change that you have to change it in a lot of different places). But the rest is fair game. Change the settings to match your horizontal and vertical refresh rates.
Then the second part is the Screen section:
Section "Screen"
Identifier "Default Screen"
Device "ATI Technologies, Inc. M9+ 5C63 [Radeon Mobility 9200 (AGP)]"
Monitor "COLOR LCD"
DefaultDepth 24
SubSection "Display"
Depth 1
Modes "1024x768" "800x600" "640x480"
EndSubSection
SubSection "Display"
Depth 4
Modes "1024x768" "800x600" "640x480"
EndSubSection
SubSection "Display"
Depth 8
Modes "1024x768" "800x600" "640x480"
EndSubSection
SubSection "Display"
Depth 15
Modes "1024x768" "800x600" "640x480"
EndSubSection
SubSection "Display"
Depth 16
Modes "1024x768" "800x600" "640x480"
EndSubSection
SubSection "Display"
Depth 24
Modes "1024x768" "800x600" "640x480"
EndSubSection
EndSection
that is what I use for my laptop. The important things are the color depth and the modes.
Pick the resolution you want and stick it in there. The color depth of '24' is the same as '32bit color' in Windows. (it's the same thing, just different ways to look at it).
Now even with those settings correct it may not work as TVs have been a bit more figity. If so you probably will have to specify modelines, which I don't know much about.
but see if you can change it so it works doing the simple way.