I overclocked my celeron 300a for science night last year...without any cooling i let the surface of the die get up to 96 degrees celcius...then i turned the machine off - nearly sh*tting a brick at the time.
Probably the hottest off hand (apart from the usual CPU and video card) without some form of cooling is the clock generator on the motherboard, and believe it or not, the EMU10K1 processor on my SBLive.
The hottest thing that I have ever encountered was my CPU. The power connector to my CPU Fan was loose and it was not cooled and it rose to abut 90-95 degrees celcius! When I wanted to touch it afterwards I nearly fried my hand when I touched it! And it was also overclocked!
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