The easiest (but probably slowest) way is to drag the icon to the start menu. Keep holding the button down, wait for the start menu to expand. Then expand all programs, then Startup. Drag the icon into that menu and release the button.
If you want to use the Add/Remove feature you can go to Taskbar and Start Menu Properties, click the Classic Start Menu button and use the Add/Remove feature. As you are exiting just click the button back to Start Menu so you don't actually switch to the classic mode.
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